Copper 8-Hydroxyquinoline (Copper Oxinate), CAS: 10380-28-6

Copper 8-hydroxyquinoline (copper oxinate, copper quinolinolate, CAS 10380-28-6) is a yellow-green crystalline powder supplied at 98% minimum content, with tight limits on chloride, sulphate and moisture. It is a chelated organic copper compound – the copper ion locked into two 8-hydroxyquinoline ligands – used as an agricultural fungicide and bactericide, and as an industrial preservative in coatings, plastics, textiles and timber.

Specification

Parameter Limit Why it matters
Appearance Yellow-green crystal powder The colour is characteristic of the chelate; a brown or dull cast suggests free copper or degraded ligand
Content 98% min The chelated copper content – the figure the formulator doses on
Chloride (Cl) 0.01% max Critical for agricultural use. Chloride is the classic cause of leaf burn with copper sprays, and it also drives corrosion in coatings and in processing equipment
Sulphate (SO4) 0.1% max Residual from the copper salt used in manufacture; affects formulation stability and phytotoxicity
Loss on drying 0.5% max Moisture affects storage stability, dispersibility in wettable powders and the assay basis

Identity and properties

Property Value Practical significance
Chemical name Bis(8-hydroxyquinolinato)copper(II) Two 8-hydroxyquinoline ligands coordinating one copper ion through nitrogen and oxygen
Formula / molecular weight C18H12CuN2O2 / about 352 Copper is roughly 18% of the molecule by mass
Appearance Yellow-green crystalline powder Distinct from the blue of inorganic copper salts – a useful visual identity check
Solubility Essentially insoluble in water; sparingly soluble in organic solvents Formulated as wettable powders and suspensions rather than solutions
Stability Stable in normal storage; decomposes in strong acid with release of the ligand Do not formulate with strongly acidic components
Copper release Slow, because the copper is chelated This is the source of its main advantage over inorganic copper – see below

Why chelated copper behaves differently

Aspect Copper 8-hydroxyquinoline Inorganic copper (Bordeaux, copper hydroxide, copper oxychloride)
Copper availability Chelated – released gradually Largely free ionic copper at application
Phytotoxicity Lower; less risk of leaf burn and fruit marking Higher, particularly in cool wet conditions and on sensitive crops
Use rate Lower, because the active is more efficient per unit of copper Higher, and limited by annual copper loading rules
Chloride sensitivity Controlled in the specification precisely because of this Depends on the salt used
Cost Higher per kilogram Lower, which is why inorganic copper still dominates by volume
Formulation Wettable powder, suspension concentrate Wettable powder, suspension, Bordeaux mixture prepared on farm

The commercial logic: chelated copper is chosen where crop safety matters more than cost per kilogram – young tissue, sensitive varieties, and programmes already close to their annual copper limit.

Applications

Sector Function Formulation note
Agricultural fungicide and bactericide Protectant against fungal and bacterial disease on fruit, vegetables and field crops Wettable powder and suspension; the grade must meet the registration requirements of the destination market
Industrial preservation of coatings Anti-mould and anti-algal additive for paints and renders Compatibility with the binder system and with other biocides has to be checked
Plastics and polymers Preservative against fungal growth in flexible PVC and similar materials Thermal stability during processing is the constraint
Textiles and leather Rot and mould resistance Often applied in a treatment bath rather than as an additive
Timber Wood preservative component Fixed in the wood rather than leached, which is the point of using a chelate
Antifouling coatings Barnacle and algae control on hulls and structures Registration and discharge rules vary widely between markets

Regulatory position

Framework What applies What the buyer must confirm
Pesticide registration Agricultural use requires registration in the destination country, with the label defining permitted crops, rates and intervals That the product is registered for your crop and market – an unregistered use is not made lawful by the raw material being available
Biocidal products Industrial preservation uses are regulated as biocidal products in many markets The product type and whether authorisation exists for that use
Copper loading limits Several markets cap total copper applied per hectare per year, particularly in organic production Whether chelated copper counts towards the cap in your market, and at what rate
Organic certification Copper compounds are restricted rather than freely permitted in organic systems Whether this specific compound is listed by the certifier you work with – do not assume
Transport and storage Classified as a hazardous substance for transport in many jurisdictions The classification and packaging your market applies

Note on claims. We supply the technical material. We do not make efficacy claims and we do not advise on crop use – the label and the registration, held by the marketing authorisation holder, define what may be claimed and how the product may be applied. Tell us the destination market and end use at enquiry so the documentation can be matched to it.

Packaging, storage and documentation

Item Detail
Packaging 25 kg fibre drums or paper sacks with PE liner; smaller packs on request
Storage Cool, dry, sealed, away from acids and foodstuffs. The powder is stable but hygroscopic at the surface; keep the liner closed
Documentation Batch COA (content, chloride, sulphate, loss on drying, appearance) plus SDS
Grade statement Technical or agricultural grade as agreed; confirm the registration status your market requires

For the comparison against inorganic copper fungicides see copper 8-hydroxyquinoline versus inorganic copper, and for preservation uses see industrial preservation with copper 8-hydroxyquinoline. The technical overview is in the copper 8-hydroxyquinoline guide.

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